Superformance is too slow , relative burn rate comparable to N165 and RS70.
N133 is an excellent choice for the 50grain in 223 as is 130 and 135 .
N540 is a high energy propellant , work up carefully and you're supposed to use the next bullet weight up for data . I suspect you'll get a low case fill which may well translate into large ES numbers . Pure speculation on my part , but please come back and share your findings.
Personally , I'm not a fan of ball powders . They meter well , but can be a little peeky . I know other people use them with excellent results , I had good results with X-terminator but definitely prefer N133 .
You could ask if an SD member would run QL for the N540 but remember there's no real shortcuts and the results are theoretical , you still need to do load development and adhere to safe practices .