I always had excellent results from N133 under 52 and 53gn match bullets (Hornady and Sierra) when I loaded a slow-twist 223 many, many years ago. I doubt if there's much if anything that would be better across the board even today and N133 also has the advantage of widespread and reliable availability and reasonable pricing.
The much more recently available Reload Swiss RS-40 would almost certainly produce higher MVs, but this is a 'hot' number.