When the firing pin hits the primer and the powder starts to burn the brass case expands in all directions till it is firmly against all the walls of the chamber, whether its the side of the barrels or the breech face. The brass case will grip the walls and will the case head back somewhat, but if there is any excess head space the brass cartridge will stretch and take this up.
By the time pressure builds towards it maximum all the brass will be firmly against all the surfaces of the chamber and case is transferring the pressure directly to the walls. Pressure of 60,000 psi will felt all surface, whether it is the breech face, walls of the barrel or base of the bullet. Given that it is a fluid gas everywhere will receive the same pressure.
As for oiling the cartridge case / chamber walls, this may well stop the case gripping the walls as well a clean case and may allow some gas leakage, but given the temperature and pressures I suggest any oil will vapourise and combust. In any case oil is a fluid that is incompressible and if it remains a fluid it will simply transmit the force to the other surfaces. Think hydraulics.