Dishwashing liquid for barrel cleaning

I use M-Pro Copper Cleaner & M- Pro CLX after. All the products so fat I've bought/used have a colour, nothing clear as yet. Any dish cleaner has an additive to break down grease/oil's & will come out emulsified in some sort grey/brownish way whatever it was.
After buying products to clean & coat the surface the last thing I'd recommend is adding any water content. I'd go with Red-X on a brush for carbon if I were to go away from approved products, clean through & re-apply my normal surface protector again. You'd be hard pushed to beat paraffin or diesel left to soak on carbon & scrubbed well.

M-Pro 7 gun cleaner/carbon remover is 75-85% water.
M-Pro 7 copper remover is over 60% water.
Bore gel: 55-65% water.

This is stated in the SDSs, see Document Library & SDS - Pantheon Enterprises chemical company scroll down to the weapon care section.

The instructions are that, after using these water based products, you must protect the bore etc with oil, they suggest their LPX gun oil.

CLX was discontinued years ago, I think that LPX is the replacement, certainly they say it has some bore cleaning capability if scrubbed on with a metal brush, but I'm not sure it has any useful chemical activity such as that of the dedicated bore cleaners.

The C2R instructions (thanks for the tip, never head of it before) say to let it soak, no brushing required, then just use wet (plain water soaked) patches to shift the loosened carbon. I'm guessing that there is a strong surfactant in the fluid to assist the process, just as dish detergent is basically surfactant, thickened with salt, and scent added. The thickening thing seems to be a British preference, elsewhere in Europe theirs is mostly thin, and to my mind often more effective.

Chloride ions (as in salt) are not good for barrel grades of "stainless" steel, better to avoid things that are stuffed full of them, no matter how cost-effective they may seem to be.

I'm also guessing that C2R have dosed it up with some sort of copper solvent or chelating agent, to serve dual purpose to try to keep on top of the copper as well as keep the carbon loose. I suspect that that may be a compromise, trying to make it into a universal one-stop solution. Everybody else seems to see these processes as separate. Or maybe they just prefer to sell two separate products for twice the price ? and the concept of never needing to use a brush, the cleaning fairies will just float it all away with a few patches is, let's say, interesting.

Well it must be so, there is no practical way to dissolve carbon, all that you can do is try to loosen it somehow by attacking the other stuff holding it together, a cocktail of perhaps initially tarry deposits, that the longer you leave them, the more baked-on they get. A bit like neglecting cleaning your oven regularly. Keep on top of it, tedious though that might be, and you may save yourself a lot of pain.

I do agree that it seems improbable that the carbon could be effectively removed without brushing, just wiped away with a few water-soaked patches. Likewise the copper and other metals from the jacket just dissolved away without any effect on the barrel steel despite lengthy soaking and no neutralisation process suggested afterwards (slightly more plausible) but I have no experience with the stuff, .perhaps it really is that good.

Cynically, I think I've heard similar things before with "foaming bore cleaners". Miraculous stuff, just a quick squirt, leave for a while, patch out, or or if really lazy just tug a boresnake through. But no substitute for trying a little harder. Frankly I suspect that just a squirt of WD40 and a regular careful rod-through with a bronze brush would be at least as effective, that's if you just want to keep on top of the carbon, but leave the de-coppering to when you think it's becoming a problem, if ever.

I haven't tracked down an MSDS for C2R yet to give some clues about the formula, but one will have to be published sometime if this is to be sold legally.

Studying MSDSs can be interesting, to get an idea about what you are dealing with. Some of the old fashioned stuff like Hoppes #9 (original, then re-formulated), Butch's (original then re-formulated), Sweets etc. is really quite scary, you certainly don't want to be using it without gloves and good ventilation, whether or not you like the nostalgic smell.

There's a lot to recommend these modern aqueous or otherwise, fairly benign, environmentally compatible biodegradeable formulations, as long as they can do a good-enough job. Better that than the toxic old formulations that come plastered with every warning sign possible, no practical way for most of us to safely dispose of even just our used patches (maybe burn them, rather than risk the stuff leaching into water courses, highly persistently toxic to aquatic life, polluting landfills etc. ) No, washing out your brushes, perhaps in the US cleaner, then flushing the residue down the drain is no longer acceptable, at least to me.

The military seem to have moved over to the newer stuff, possibly simply for pragmatic reasons of easier procurement, transport, storage, worker safety, disposal, maybe even effectiveness and ease of use. E.g the stuff that Pantheon Enterprises developed for the military, and supply by the oil-drum full, their armourers just dunk entire weapons into tanks of it, maybe scrub them a bit or ultrasonic, drain, dry, dunk in the oil, drain, job done.

Study the MSDS for the M-Pro 7 gun cleaner/carbon cleaner, and you will soon realise that it is just water, with a named, presumably very strong, surfactant, maybe a few other things too, undeclared. They are not required too either because they have stated that it's entirely hazard free, biodegradeable. Probably a lot better than diluted Fairy Liquid, but basically same principle. If you have contacts you might be able to get your hands on really strong pure surfactants. E.g. the stuff laboratories use for cleaning glassware, or nuclear decontamination.

The Pantheon stuff gets put into little bottles, branded, and sold to us at huge margins by Bushnell, who also sell it as Hoppes Elite, which I think is exactly the same stuff.

I once knew a chap who was so tight that he'd re-use his old patches and bits of 4x2 by putting them into the washing machine in a calico bag, along with the household wash. Even then I didn't think that was very clever, now I'd say it was borderline insane to expose himself and family to the chemicals, metals, gunshot residue, God knows what, by impregnating their clothes with it, to save a few bob.

Now my big bottle of original Butches' that will last me a few years more, came in a glass bottle (no usual plastic can contain it long term), contained in a polycarbonate outer/bund, double bubble wrapped, double boxed, even back then I'm pretty sure it shouldn't have been posted. It's the original formulation though, not the less effective re-formulated version. When it runs out I won't be replacing it, meanwhile there's no doubt that it still works very effectively, and I bought far too much, being inexperienced as to how little you really need to use if you work sensibly. And I can't think of a way of safely disposing of it, other than by using it up.

If you really want to see how toxic this stuff is, here's a link to the MSDS. It seems Butch just chucked in everything he could think of, preferably a benzene compound. Even back then we knew that was not a good idea. Read it and weep, it's probably the scariest one that I have read, and I've still got a significant quantity of it that worries me a little to have about the place. Original Hoppes #9 was nearly as bad. I still have an ancient bottle of the original too. It seems that I'm the habit of over-buying.

 
Folks including me used to wash out rifle barrels with water. Boiling if we could. Hot if we couldn't get a pan or kettle to boil it and if it was just plain cold water that was available then you used that. Then a 1:3 mix of Young's .303 and water to make "aquoil". All an absolute necessity in the days of mercuric primers. On a muggy day if you din't you'd have rust in the bore within a matter of hours.
 
Folks including me used to wash out rifle barrels with water. Boiling if we could. Hot if we couldn't get a pan or kettle to boil it and if it was just plain cold water that was available then you used that. Then a 1:3 mix of Young's .303 and water to make "aquoil". All an absolute necessity in the days of mercuric primers. On a muggy day if you din't you'd have rust in the bore within a matter of hours.

Still some merit in starting off pouring through a kettleful of boiling water. Even nowadays, though the primers and other stuff may not be corrosive in the same way, the powder residue and condensation in the moderator still contain large quantities of hygroscopic nitrogen compounds that soon turn into various nitric and nitrous acid compounds, hence the stern warnings about leaving the mod. on in the cabinet, and the rot that will probably ensue. That's what smokeless powder is made of. Black is different, but has quite different challenging residues, that can also mostly be simply flushed away with hot water.

When I used to shoot black powder, I used boiling water, followed by a fairly dilute emulsion of soluble/miscible lathe coolant/cutting fluid whilst still hot, which I got free. That stuff must have had some pretty good corrosion inhibitors, you could spray it all over very expensive lathes, mills, beds, chucks, tooling, leave it for days, never the least sign of rust. A quick patch out before use, sometimes not even that, if anything it helped keep the powder residues soft, so I used it to swab the bore every few shots.

Sounds like "aquoil" but a fraction of the cost for an industrial sized container ...

I don't think I have any left, but it's easy enough to find on e.g. Ebay, and possibly even better these days.
 
Folks including me used to wash out rifle barrels with water. Boiling if we could. Hot if we couldn't get a pan or kettle to boil it and if it was just plain cold water that was available then you used that. Then a 1:3 mix of Young's .303 and water to make "aquoil". All an absolute necessity in the days of mercuric primers. On a muggy day if you din't you'd have rust in the bore within a matter of hours.

My dad told me about how my grandfather used to clean his .303 using this method. Asked if it was the same for new rifles.
 
M-Pro 7 gun cleaner/carbon remover is 75-85% water.
M-Pro 7 copper remover is over 60% water.
Bore gel: 55-65% water.

This is stated in the SDSs, see Document Library & SDS - Pantheon Enterprises chemical company scroll down to the weapon care section.

The instructions are that, after using these water based products, you must protect the bore etc with oil, they suggest their LPX gun oil.

CLX was discontinued years ago, I think that LPX is the replacement, certainly they say it has some bore cleaning capability if scrubbed on with a metal brush, but I'm not sure it has any useful chemical activity such as that of the dedicated bore cleaners.

The C2R instructions (thanks for the tip, never head of it before) say to let it soak, no brushing required, then just use wet (plain water soaked) patches to shift the loosened carbon. I'm guessing that there is a strong surfactant in the fluid to assist the process, just as dish detergent is basically surfactant, thickened with salt, and scent added. The thickening thing seems to be a British preference, elsewhere in Europe theirs is mostly thin, and to my mind often more effective.

Chloride ions (as in salt) are not good for barrel grades of "stainless" steel, better to avoid things that are stuffed full of them, no matter how cost-effective they may seem to be.

I'm also guessing that C2R have dosed it up with some sort of copper solvent or chelating agent, to serve dual purpose to try to keep on top of the copper as well as keep the carbon loose. I suspect that that may be a compromise, trying to make it into a universal one-stop solution. Everybody else seems to see these processes as separate. Or maybe they just prefer to sell two separate products for twice the price ? and the concept of never needing to use a brush, the cleaning fairies will just float it all away with a few patches is, let's say, interesting.

Well it must be so, there is no practical way to dissolve carbon, all that you can do is try to loosen it somehow by attacking the other stuff holding it together, a cocktail of perhaps initially tarry deposits, that the longer you leave them, the more baked-on they get. A bit like neglecting cleaning your oven regularly. Keep on top of it, tedious though that might be, and you may save yourself a lot of pain.

I do agree that it seems improbable that the carbon could be effectively removed without brushing, just wiped away with a few water-soaked patches. Likewise the copper and other metals from the jacket just dissolved away without any effect on the barrel steel despite lengthy soaking and no neutralisation process suggested afterwards (slightly more plausible) but I have no experience with the stuff, .perhaps it really is that good.

Cynically, I think I've heard similar things before with "foaming bore cleaners". Miraculous stuff, just a quick squirt, leave for a while, patch out, or or if really lazy just tug a boresnake through. But no substitute for trying a little harder. Frankly I suspect that just a squirt of WD40 and a regular careful rod-through with a bronze brush would be at least as effective, that's if you just want to keep on top of the carbon, but leave the de-coppering to when you think it's becoming a problem, if ever.

I haven't tracked down an MSDS for C2R yet to give some clues about the formula, but one will have to be published sometime if this is to be sold legally.

Studying MSDSs can be interesting, to get an idea about what you are dealing with. Some of the old fashioned stuff like Hoppes #9 (original, then re-formulated), Butch's (original then re-formulated), Sweets etc. is really quite scary, you certainly don't want to be using it without gloves and good ventilation, whether or not you like the nostalgic smell.

There's a lot to recommend these modern aqueous or otherwise, fairly benign, environmentally compatible biodegradeable formulations, as long as they can do a good-enough job. Better that than the toxic old formulations that come plastered with every warning sign possible, no practical way for most of us to safely dispose of even just our used patches (maybe burn them, rather than risk the stuff leaching into water courses, highly persistently toxic to aquatic life, polluting landfills etc. ) No, washing out your brushes, perhaps in the US cleaner, then flushing the residue down the drain is no longer acceptable, at least to me.

The military seem to have moved over to the newer stuff, possibly simply for pragmatic reasons of easier procurement, transport, storage, worker safety, disposal, maybe even effectiveness and ease of use. E.g the stuff that Pantheon Enterprises developed for the military, and supply by the oil-drum full, their armourers just dunk entire weapons into tanks of it, maybe scrub them a bit or ultrasonic, drain, dry, dunk in the oil, drain, job done.

Study the MSDS for the M-Pro 7 gun cleaner/carbon cleaner, and you will soon realise that it is just water, with a named, presumably very strong, surfactant, maybe a few other things too, undeclared. They are not required too either because they have stated that it's entirely hazard free, biodegradeable. Probably a lot better than diluted Fairy Liquid, but basically same principle. If you have contacts you might be able to get your hands on really strong pure surfactants. E.g. the stuff laboratories use for cleaning glassware, or nuclear decontamination.

The Pantheon stuff gets put into little bottles, branded, and sold to us at huge margins by Bushnell, who also sell it as Hoppes Elite, which I think is exactly the same stuff.

I once knew a chap who was so tight that he'd re-use his old patches and bits of 4x2 by putting them into the washing machine in a calico bag, along with the household wash. Even then I didn't think that was very clever, now I'd say it was borderline insane to expose himself and family to the chemicals, metals, gunshot residue, God knows what, by impregnating their clothes with it, to save a few bob.

Now my big bottle of original Butches' that will last me a few years more, came in a glass bottle (no usual plastic can contain it long term), contained in a polycarbonate outer/bund, double bubble wrapped, double boxed, even back then I'm pretty sure it shouldn't have been posted. It's the original formulation though, not the less effective re-formulated version. When it runs out I won't be replacing it, meanwhile there's no doubt that it still works very effectively, and I bought far too much, being inexperienced as to how little you really need to use if you work sensibly. And I can't think of a way of safely disposing of it, other than by using it up.

If you really want to see how toxic this stuff is, here's a link to the MSDS. It seems Butch just chucked in everything he could think of, preferably a benzene compound. Even back then we knew that was not a good idea. Read it and weep, it's probably the scariest one that I have read, and I've still got a significant quantity of it that worries me a little to have about the place. Original Hoppes #9 was nearly as bad. I still have an ancient bottle of the original too. It seems that I'm the habit of over-buying.

TBH I am not so much concerned about the ecological footprint of Fairy Liquid or any other cleaner, but whow, what an essay!!!! Thank you for this!!

I am much more interested in what really works. And it seems that the surfuctants in washing up liquid really do have a cutting edge.
 
Thanks for the hint. I didn't know the CR2. Your link doesn't work though.
But CR2 is a combined cleaner against carbon and copper fouling. This is fine to be used on patches and nylon brushes but it will eat away bronze brushes. I dare say there is NO cleaner in the world that will remove the carbon fouling in barrels all by its own. You will always need a bronze brush. And for this a copper neutral cleaner is required.

2nd go: C2R Cleaner – The UK Rifle Barrel Bore Cleaner

You don't scrub with C2R -a big part of the USP, you just leave the solution to get on with it-, thus no brushes are required, just patches to apply and remove the solution; and Tipton do a non-brass jag set, so no brass/bronze need get harmed in the process. (A.k.a. you do not always need a bronze brush.)

P.S. Sorry... missed a few posts there!
 
..
but whow, what an essay!!!! Thank you for this!!

I am much more interested in what really works. And it seems that the surfuctants in washing up liquid really do have a cutting edge.

Couldn't sleep last night, so occupied myself doing some research.

Actually I may have got it wrong about M-Pro 7 cleaner being mostly surfactant, it might mostly have solvent action.

Active ingredient Diethylene Glycol Monobutyl Ether, 14%, the rest water. Dow Chemical are a big supplier, they have their own brand which they call Butyl Carbitol. Seems to be benign eco-friendly stuff.


FWIW I could buy one litre of pure lab-grade > 99% DGBE for about £25, that would be enough to mix up over 7 litres of cleaner. Industrial grade stuff, a fraction of the price.

7 litres of e.g. M-Pro 7, in 4 US fl.oz bottles, at £15 each would retail for, ooh, £831.

As for surfactants, well they are not all the same, far from it, here's probably more information than you want to know:


If e.g. Fairy Liquid really works, great. It will be a non-ionic surfactant, and apart from the salt content I can't foresee any problems, as long as you protect the bore from rust after using it.

If having a try at this, I'd start by looking at Decon 90, you can get a litre for £12 or so, might seem pricey compared with Fairy Liquid, but it's quite different, highly concentrated, and if it doesn't get stuff squeaky clean (as in radiogical decontamination), then I doubt anything else will. Otherwise good old Teepol L, still the standard for cleaning laboratory glassware.

If the experiment doesn't work out, long-term, well you can always return to the many and varied proprietary concoctions, about which some have their dogmatic preferences, as in "I've always used product X, I think its the best. No I've not tried much else, I can't afford to experiment with the alternatives, anyway a bottle lasts me years, I like the healthy smell of benzene, amyl acetate, ammonia, acetone etc. It's got a re-assuring retro label and packaging, even though I realise that chemically it's nothing like the original stuff that I grew up with, not even manufactured by the original company, and enjoy the slow laborious ritual with the brushes, jags, patches etc. that others have tested and found that it was borderline effective at best, compared with more modern stuff"

Next research project: alternative de-coppering (and zinc, tin, lead etc.) barrel-safe formulae compared with the old smelly but proven aqueous ammonia method. I can think of several straightforward etchants that would get it out almost in seconds at the concentrations that I'm used to, but they might also go for barrel steels in minutes or hours, so not really practical. Unless, maybe, diluted or otherwise restrained. There are other mechanisms to get these metals into solution, but I know little about them.

If I could figure out something much better than what's already on offer, manage to develop it, test it, refine the formula, believe in it personally, promote it, distribute it, jump through the elf and safety stuff, pay for the little bottles and labels (much more costly than the content), employ people to mix it up, package, post it out, warehouse stock, manage cashflow, then I certainly wouldn't be trying to compete with anyone on price, that would be rude and counter-productive, rather justify the stuff on superior performance, which would be difficult to prove. Many ways to clean a bore, many opinions, as with most gunnery things they've mostly all been tried before, long ago.

Kudos to e.g. the Shooting Shed lot with their C2R, I doubt that they are going to become wealthy from it, but at least they have put it out there for us to have a try.

Of course, the whole cleaning your rifle business may not be entirely necessary, particularly for stalkers, once you look into it, but the paraphernalia, consumables and so on add up to a considerable high-margin business for the trade, that isn't going to be replaced by retro boiling water, Fairy Liquid, meths, a pull-through, 4x2 on a jag, some simple gun oil (actually good motor oil is far more sophisticated than any "gun oils" these days, and full of good corrosion inhibitors) and a good scrubbing now and then with a bronze brush, even though that seemed to work well enough in the past.

PS: it seems that the new Hoppes is now also made for Bushnell by Pantheon, if I've understood correctly. And the "Elite" version perhaps the same thing as M-Pro.

Being realistic, it's just a lot easier for most to buy whichever bottle of cleaner is locally available, you don't need that much, and AFAIK they mostly work, perhaps some better than others, but most of the reviews are anecdotal. Researching what's in them and how they work is interesting to me, nevertheless I don't intend to try making my own, unless I happen to have the chemicals on-hand and nothing better to do with my time.

My ridiculously big bottle of nasty original Butch's, and smaller one of original Hoppes #9 will probably see me out at the rate I use them, or if I inhale too much, whichever comes first.
 
2nd go: C2R Cleaner – The UK Rifle Barrel Bore Cleaner

You don't scrub with C2R -a big part of the USP, you just leave the solution to get on with it-, thus no brushes are required, just patches to apply and remove the solution; and Tipton do a non-brass jag set, so no brass/bronze need get harmed in the process. (A.k.a. you do not always need a bronze brush.)

P.S. Sorry... missed a few posts there!

So they say.

What is your personal experience with it ?
 
Good to see that this bringing up some humor.
But seriously, I have not seen a ‚proven‘ solvent that really does the job properly. Unfortunately I cannot take any pictures with my borescope.

I can assure you they do exist - not sure there'd be any point mentioning them!:doh::)
 
I used to clean my barrels with WD40 until I changed to Bore Tech, but I still finish the cleaning with WD40. I also clean my black powder shotgun barrels with WD40 and never had a problem.
 
Recently bought a stainless 243 donor action. The original barrel was still fitted so I wanted to see what she looked like before barrel change. I started cleaning with Hoppes and Otis but patches were very very dirty ...… and did not get better. It looked as if the rifling was gone in the first section. I remembered this thread and got a good fitting copper brush and some of the lidl power max spray bottle kitchen cleaner, flushed the barrel with the cleaner and gave it a few strokes. A lot of dirt came out and after rinsing with almost boiling water the barrel was spotless .... rifling was crystal clear again . I did run a few patches with some Hoppes on after to give a some protection. Rifle shot fine yesterday eve. This will save a lot of messing around in the future.
edi
 
the hands that do barrels are as soft as you like with mild green ........................................................................ swarfega
 
…. the lidl power max spray bottle kitchen cleaner.....

That was brave of you!
I had also tried a similar product which actually gave me rust stains in the chamber. I had to polish them out afterwards.
Bath and kitchen cleaners seem to be very agressive on black steel.
 
That was brave of you!
I had also tried a similar product which actually gave me rust stains in the chamber. I had to polish them out afterwards.
Bath and kitchen cleaners seem to be very agressive on black steel.
Was a stainless barrel and action, that lidl stuff is used all the time on stainless steel. Trick is also to flush it off quick afterwards. Just had the barrelled action at hand, no stock or scope. Did the same on a new custom barrel yesterday and also turned out really good. Some amount of black came out, after rinsing, drying and blowing all out with an air gun I used Otis copper solvent. Two three blue patches came out. Recon the scrub took out the carbon leaving the copper blank.
edi
 
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