Sam, just approach the search for land as a business marketing campaign.
It is all about personal relationships, introductions, recommendations and building trust.
A good way into getting land, for example, is to built a relationship with a farm that has a retail shop on site to sells their produce. Established yourself as a regular good customer paying good money (cash is best) for their produce and come in regularly so they get to know you. Through the usual smalltalk establish who is in charge and find out their names. Built a relationship of trust. Then do your background research into the land and farm and access etc using various internet resources and mapping sites.
Then, and only then, mention about the rabbits/foxes/deer/pigeons you always spot on their land, how much damage they must do, how much money they must loose, and casually mention you do a bit of shooting and that you would love to help them out keeping their vermin under control. Once they have said 'Yes, ok than' as it will be difficult for them to refuse a good trusted local customer) make sure you draft a permission letter so they just have to sign it, deliver the letter by hand and wait for them to sign it and hand it back to you. Quote insurance/H&S reasons for the written permission requirement.
Don't even mention the deer yet - at this point we are looking at rabbits, pigeons and maybe foxes.
Once you have been on a farm for a few years and have shown your commitment and have results, only than could you try to add deer to your list. Most landowners/farmers are very secretive and protective of the deer so don't expect to get deer shooting permission just like that.
And once you are established on a farm you are likely to be introduced to the neighbouring farmers and things can start rolling from there.
Other methods, some or all you can do concurrently with the above suggestion:
1. Simply pay for a shooting lease. Generally a lot.
2. Network and befriend other stalkers to get invitations and more experience, offer to help but not shoot. The shooting bit will come later.
3. Join a beaters team of a local shoot and you will be surprised by the amount of people you meet, in particular under the beaters, who are often very much more advanced and experienced with guns and rifles than the 'guns' of the shoot. Making friends there will open many doors for you, eventually.
4. Join a target/rifle club where you can use your deer rifle. The practice and range where you can check your zero under controlled conditions is always useful and again it offers many networking opportunities.
5. Enroll on courses (DSC1, LANTRA) as you meet like minded people who will offer you opportunities, and the paper qualifications also help when asking for permission. In fact in many cases you need qualifications now before the landowner will even talk to you.
Just be aware that a hard-won permission can be easily lost if you show no results, don't show up, do things against their wishes and bring other people on the land without their specific permission. Some permissions you can loose simply because someone else puts lots of cash on the table. So don't put all your chickens in one basket.
Good luck - if you show tenacity you will get those permissions!