I don't think it is worth the cost of getting a rifle rechambered to an AI case (with a few exceptions - 257 Bob being the best known exception), but if you are rebarreling and already reloading there is not necessarily any reason not to go AI. You will not see any significant effect on accuracy, but some cases do benefit from decreased stretch - the 243 AI being one of the better known examples.Your fireforming loads can still be effective hunting loads - for example a lot of folks use fairly useful varmint loads for fireforming 223 AI brass.
The rule is that for any increase in case capacity, the increase in muzzle velocity will typically be 25% of the increase capacity. Most cases yeild increases in capacity of 4 to 8%, and so you get a 1 to 2% increase in muzzle velocity. Obviously a lot of folks achieve greater increases, but they are achieving their gains by running at higher pressures rather than greater capacity. In reality, much of the success of AI cases is actually due to parent cartridges being loaded to lower pressures - and that extends even to some of the more modern cases such as 223 (which is SAAMI 56000PSI) and 243 (60000PSI - when testing the 243 case they found pressures varied a lot as it is a little overbore and hence to reduce pressures a little vs other 308-based cartridges to be confident factory ammunition on average would remain under the safe limits. The 7mm Rem mag is similar).
You also need to consider your feed system - AIed cases are much better feed from single-column midline feed magazines, and may cause problems in a more traditional mauser-type action with a staggered column. And generally, more reliable feed is actually of greater practical advantage than 50-100fps in a hunting rifle. Remember, even the big-daddy of long range bolt-action cartridges, the 338LM, still has a fair bit of taper to it - and the military guys know what they are doing. Reliablity matters.
Is it worth while? Well only you can answer that, but i do find it very amusing that many folks would tell you that the 30-06 is a very much better all-around hunting round than the 308, but laugh at the suggestion of taking a 30-06 up to a AI case. However, there is in fact a greater difference between the 30-06 and the 30-06 AI than there is between the 308 and 30-06! And the 30-06 requires an extra half a pound in the action - yet somehow that is worthwhile and AI is stupid. Also consider the difference between a 308 and 30-06 is effectively about 25 yards ie: a 30-06 is doing at 325 yards what a 308 is doing at 300 yards. ie: bugger all!